| abstract |
PCT No. PCT/US98/20801 Sec. 371 Date Jun. 3, 1999 Sec. 102(e) Date Jun. 3, 1999 PCT Filed Oct. 2, 1998 PCT Pub. No. WO99/18044 PCT Pub. Date Apr. 15, 1999A corrosion-inhibiting composition for application to a metal substrate, such as steel, silver, copper or aluminum, includes a film-forming organic polymer component and a dispersed pigment phase of a stable unitary hybrid which contains organic and inorganic solid phase constituents interfaced at a micro-crystalline level, which are inseparable by physical separation procedures and which display uniphase behavior. The inorganic phase includes a cation selected from Zn, Al, Mg, Ca, Sr, Ti, Zr, Ce and Fe and an anion selected from phosphates, polyphosphates, phosphites, molybdates, silicates and cyanamides. The organic phase includes zinc or alkyl-ammonium (for example: cyclohexyl-ammonium, di-cyclohexyl-ammonium, octyl-ammonium) salts of organic mercapto- and thio-compounds or their alkyl-substituted derivatives, as follows: mercaptobenzothiazole, mercaptothiazoline, mercaptobenzimidazole, mercaptoimidazole, 2,5-dimercapto-1,3,4-thiodiazole, 5,5-dithio-bis(1,3,4-thiadiazole-2(3H)-thione, mercaptobenzoxazole, mercaptothiazole, mercaptotriazole, mercaptopyrimidine, mercaptopyridine, mercaptoquinoline, alkyl- and cyclo-alkyl mercaptanes, -alkyl- or N-cycloalkyl-dithiocarbamates, O-alkyl- or O-cycloalkyl-dithiocarbonates, O,O-dialkyl- and O,O-dicycloalkyl-dithiophosphates. |