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filingDate 1998-03-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2000-08-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_495d5103a64a1c96fba7068e059317b0
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f78934fce2224974587fcdf19bfef163
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publicationDate 2000-08-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-6107401-A
titleOfInvention Process for producing amine functional derivatives of poly (vinyl alcohol)
abstract This invention relates to a process for producing an aminoalkylal derivative of polymer containing a plurality of polymerized vinyl alcohol units which are vicinal, preferably a process for producing the 4-aminobutyral of poly(vinyl alcohol). The improved process for the amino-acetalization of such polymers described herein comprises reacting a 5 of 6 member cyclic imine of the structure wherein n is an integer from 3 to 4 with the polymer containing a plurality of polymerized vinyl alcohol units. In a preferred reaction, 1,2-pyrroline is reacted with the polymer containing polymerized vinyl alcohol units under acidic conditions. Preferably the reaction is carried out by a slurry phase process employing a non solvent carrier such as methanol for the poly(vinyl alcohol). The reaction scheme for preparing the 4-aminobutyral of poly(vinyl alcohol) may be characterized by the following equation.
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