http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6087085-A

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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/G03C1-0051
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filingDate 1998-10-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2000-07-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_587a9cfd5c87cc7b7a949b38c875ab8a
publicationDate 2000-07-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-6087085-A
titleOfInvention Preparation method of morphologically homogeneous (111) tabular crystals rich in silver bromide
abstract A method is disclosed for preparing an emulsion having grains rich in silver bromide in the presence of gelatin as a protective colloid in a reaction vessel wherein a yield of more than 250 g of precipitated silver nitrate per liter of reaction vessel mixture is attained, wherein at least 70% of a total projected area of all grains is provided by {111} tabular grains having an average aspect ratio of more than 2:1 and an average thickness of from 0.05 up to 0.30 mu m and wherein a ratio by number of percentage amounts of hexagonal tabular grains to triangular tabular crystals present is more than 10:1, said method comprising following steps: preparing in a reaction vessel a gelatinous dispersion medium containing an initial amount of oxidized gelatin corresponding with less than 50% of a total amount of gelatin used in the said method, and said dispersion medium having a volume of less than 2 liter per 500 g of silver nitrate to be precipitated; precipitating therein silver halide crystal nuclei by double-jet precipitation of an aqueous silver nitrate and an aqueous solution comprising halide ions, wherein less than 10% by weight of a total amount of silver nitrate used is consumed; adding to said reaction vessel gelatin in an amount of more than 50% of a total amount of gelatin used in the said method; growing said silver halide crystal nuclei by further precipitation of silver halide by means of double-jet precipitation of an aqueous silver nitrate solution and an aqueous solution comprising halide ions, wherein more than 90% by weight of a total amount of silver nitrate is consumed, concentrating by ultrafiltration the said reaction mixture volume in the said reaction vessel obtained during precipitation growth steps.
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