abstract |
PCT No. PCT/JP96/02942 Sec. 371 Date Jun. 25, 1998 Sec. 102(e) Date Jun. 25, 1998 PCT Filed Oct. 8, 1996 PCT Pub. No. WO97/24307 PCT Pub. Date Jul. 10, 1997A manufacturing method for 1,1,1,3,3-pentafluoropropane comprises a first process, in which 1,1,1-trifluoro-3-chloro-2-propene is obtained by inducing a reaction between 1,1,1,3,3-pentafluoropropane and hydrogen fluoride in the vapor phase, and a second process, in which the 1,1,1,3,3-pentafluoropropane is obtained by inducing a reaction between 1,1,1-trifluoro-3-chloro-2-propene and hydrogen in the vapor phase, and 1,1,1-trifluoro-3-chloro-2-propene obtained in the first process is supplied to the second process after removing the HCl by-products. This invention can provide a new economic manufacturing method of 1,1,1,3,3-pentafluoropropane with high yield and selectivity. |