Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_a927f9b1dabeb76a843319cb18c6291f http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_27d960dc31b15f31e687909b86a727b0 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01D53-8662 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J23-96 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J38-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J38-10 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J38-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J38-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/A62D3-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J23-96 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01D53-86 |
filingDate |
1995-07-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate |
1998-09-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f145876d4a28342a81faf5ff92c9b27e http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f53ba3c2dcef9995bab69550096ec843 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1209de1ea9026e23377edefaf6903c3f http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ecb890f3c97a428c6db58a76d6004d4d http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9e0adbb82b8d1f49f8fdb5684a60e249 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_922477db3b79952eae1f3e429b716500 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_91cd8e89f9be6a71452d07d12c8f2be6 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1f317901bdff80a699325043feeed4d2 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d065cf2790e7afe93e1d16329a95ddef http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bfd7f763d2ca1d585ea3328c58132135 |
publicationDate |
1998-09-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
US-5811628-A |
titleOfInvention |
Method for the complete hydrodechlorination of chlorinated hydrocarbons |
abstract |
A method for the hydrodechlorination of a reaction gas primarily composed of chlorinated hydrocarbons is carried out sequentially. A first step is advantageously carried out in a tubular reactor filled with catalyst and cooled externally, to maintain a temperature within a preferred range of 80 DEG to 230 DEG C. and a radial temperature difference of not more than 40 DEG C. Hydrogen is added to the tubular reactor with a hydrogen excess in a preferred range of 1.1 to 1.5 relative to the reaction gas, based on the stoichiometric consumption. The catalyst is present in a catalyst loading in a preferred range of 0.1 to 1.5 v/vh based on the volume of reaction gas. A fixed bed reactor is advantageously used for a second step, optimally connected in straight transit with the output of the reactor of the first step. The full-space reactor is maintained at a temperature within a preferred range of 200 DEG to 300 DEG C. and a hydrogen excess relative to the stoichiometric consumption is in a preferred range of 2 to 100. Catalyst is present in a preferred amount related to a volume of catalyst in step one according to a ratio in a range of 2:1 to 10:1. The dechlorination is preferably carried out at pressures between 1 and 50 bar. A method is further provided for regenerating deactivated catalysts without accumulation of dioxin in the waste gas, achieved by a reducing treatment, followed by an oxidizing treatment at a temperature at or above the last operating temperature of the catalyst. |
isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-11596927-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-8501989-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2011218318-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9808790-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-10807074-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2010317825-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9434709-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-8927768-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2458030-C1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9156766-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-8785683-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9770705-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9174911-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-8669397-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-8669393-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2010317823-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2010317822-A1 |
priorityDate |
1994-07-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |