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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F12-08
filingDate 1996-07-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1997-09-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1997-09-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-5665833-A
titleOfInvention Method for controlling a polymerization rate of styrene resins
abstract The method for controlling a polymerization rate, in a continuous radical polymerization of mainly styrene monomer using a complete mixing type reactor, without substantially changing an average molecular weight of a polymer formed, comprising the steps of: (a) keeping a polymerization temperature substantially constant at t( DEG C.), (b) setting a feeding rate of the styrene monomer to A times larger rate than that in a polymerization conducted in the absence of a radical polymerization initiator, and (c) controlling an amount of the radical polymerization initiator added in the range of from (0.1/n)x10-3 to (2.0/n)x10-3 mol per 1 liter of the monomer, n being a number of radical generating functional groups present in one molecule of the radical polymerization initiator, such that a polymer concentration x satisfy the mathematical expression: x>/=0.3t+6x(A-1)+12 and that x be kept substantially constant, wherein A represents a ratio of a polymerization rate after being controlled to a rate of polymerization conducted in the absent of the radical polymerization initiator. The method can easily and as desired control the polymerization rate using any desired radical polymerization initiator.
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