http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5616217-A

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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C41-44
filingDate 1995-08-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1997-04-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f4f71231d4c44e98aa3db362e6d1efce
publicationDate 1997-04-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-5616217-A
titleOfInvention Controlled alkali treatment in the recovery of methyl tertiary butyl ether
abstract In the manufacture of MTBE from TBA and methanol, acidic by-products formed during the etherification reaction are removed by fractionating the etherification reaction product in a first MTBE distillation column to provide a first lower boiling distillation fraction comprising isobutylene, MTBE, methanol and acidic by-products and a first higher boiling distillation fraction comprising methanol, TBA and water, fractionating the first higher boiling distillation fraction in a recycle distillation column to provide a lower boiling TBA recycle fraction and a higher boiling water fraction, recycling the higher boiling water fraction to the MTBE distillation column at a charge point above the charge point for the etherification reaction product, and adding aqueous sodium hydroxide to the recycled higher boiling water fraction in an amount sufficient to neutralize the acidic by-products charged to the MTBE distillation column.
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priorityDate 1995-08-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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