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publicationDate 1996-12-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-5583260-A
titleOfInvention Method of influencing the cis/trans isomer ratio of isophoronediamine in its preparation from isophoronenitrile
abstract A method of controlling the cis/trans isomer ratio in the preparation of isophoronediamine by the aminating hydrogenation of isophoronenitrile in the presence of ammonia, H2 and a catalyst. The reaction takes place in two temperature steps, initially at 10 DEG to 90 DEG C. and then at above 90 DEG to 150 DEG C. with a temperature difference of at least 30 DEG C. between the two steps, the contact time being shorter in the first step than in the second. The cis/trans ratio is increased by lowering the temperature of the first step.
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