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filingDate 1995-03-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1996-02-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9040fd1a86eb115882b0b797db09e7b0
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publicationDate 1996-02-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-5491250-A
titleOfInvention Process for purifying vinylically unsaturated compounds prepared using a palladium-complex catalyst
abstract A crude vinylically unsaturated product formed from a palladium-complex-catalyzed reaction of a reactant halide selected from the group consisting of aryl, allyl, vinyl, and benzyl halides, and a reactant olefin having a vinylic hydrogen, wherein the reaction is carried out in the presence of a hydrogen halide acceptor, is purified by first contacting the crude product with a base that is stronger than the hydrogen halide acceptor, then heating the stronger base-contacted product. The purified product shows a marked reduction in concentration bromine and palladium impurities. The product can then be further purified by such methods as chromatography, crystallization, or distillation to achieve a product that is more suitable for applications where very low levels of inorganic impurities are required.
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