http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5484949-A
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_e7962109cd4763907b82b66760cd0ae8 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D335-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D309-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D307-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-72 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D309-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-72 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D307-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D335-02 |
filingDate | 1994-03-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 1996-01-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9254ca4c4e47c345d506d10b51b64ef5 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a74c0f775f550b36a83754cf4fc360ab http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f2ce8cde59694604c2bf802bbae19e6e http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_969c29f25d86c0c4c1617956dde791ed |
publicationDate | 1996-01-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-5484949-A |
titleOfInvention | Method for the synthesis of α β-unsaturated ketones |
abstract | The present invention relates to a method for the synthesis of alpha , beta -unsaturated ketones which comprises, in the method for the synthesis of alpha , beta -unsaturated ketones represented by general formula <IMAGE> reacting aldehydes represented by general formula R1CHO (where R1 is as defined above) with alkali metal salt of acetoacetic acid represented by general formula <IMAGE>sence as a catalyst of 3-azabicyclo[3,2,2]nonane, a cyclic secondary amine represented by general formula (1) <IMAGE> (1) a cyclic secondary amine represented by general formula (2) <IMAGE> (2) (where, l is 1 or more and up to 6, a ring with N is a 6-membered, 7-membered or 8-membered ring, the two neighbors of N are methylene, R3 is a lower alkyl group, its substitution position is at a carbon atom other than two those adjacent to N, and <IMAGE> is an alicyclic group or a phenol group), or a secondary amine represented by general formula (3) CH3NHCH2R4(3) in a mixuture solvent of water and water-insoluble organic solvent, while keeping the pH constant with mineral acid, and by adjusting an amount of water. |
priorityDate | 1993-01-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 307.