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grantDate 1996-01-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1996-01-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-5480852-A
titleOfInvention Phillips catalyst and its use for the preparation of ethylene/alpha-olefin copolymers
abstract A novel Phillips catalyst for the copolymerization of ethylene with alpha -olefins, contains, as a catalytically active component, a finely divided, aluminum silicate-supported, phosphorus-containing chromium catalyst. This can be prepared by applying at least one organic phosphorus(III), (IV) and/or (V) compound and at least one chromium(III) compound which does not react with said phosphorus compounds under the reaction conditions used, in succcession in any order or simultaneously, to a finely divided aluminum silicate hydrogel or xerogel with formation of a catalyst intermediate and activating the catalyst intermediate at elevated temperatures in an oxidizing atmosphere, with the result that the chromium catalyst is formed. The novel Phillips catalyst gives ethylene/ alpha -olefin copolymers in which the comonomers are more uniformly distributed over the copolymer chains than is the case with ethylene/ alpha -olefin copolymers which have been prepared with the aid of conventional Phillips catalysts. Moldings which have been produced from the ethylene/ alpha -olefin copolymers obtained in the novel procedure have a particularly high environmental stress cracking resistance and an excellent creep rupture strength.
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