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grantDate 1995-12-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1995-12-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-5475055-A
titleOfInvention Thermoplastic molding material with a matt effect
abstract A thermoplastic molding material containing, based on the sum of its constituents A, B and C, n A: 70 to 99% by weight of a thermoplastic resin A comprising, based on A, n A1: 50 to 100% by weight of a hard matrix A1 comprising, based on A1, n A11: 50 to 95% by weight of units of an aromatic vinyl compound or methyl methacrylate or their mixtures (A11) and n A12: 5 to 50% by weight of units of acrylonitrile A12; n A2: up to 50% by weight of a rubber-elastic particulate graft copolymer A2 comprising, based on A2, n A21: 30 to 80% by weight of at least one elastomeric graft base A21 having a median particle size of from 30 to 1000 nm comprising, based on A21, n A211: 50 to 100% by weight of units of a 1,3-diene or a C 4 -C 8 alkyl acrylate forming rubber-elastic polymers (A211), n A212: up to 50% by weight of units of at least one vinyl monomer A212; n and n A22: 15 to 85% by weight of a graft shell A22 comprising, based on A22, n A221: 50 to 90% by weight of units of an aromatic vinyl monomer A221 and n A222: 10 to 50% by weight of units of acrylonitrile A222; n B: 0.5 to 15% by weight of a nitrile rubber B comprising, based on B, n B1: 10 to 40% by weight of units of acrylonitrile, and n B2: 60 to 90% by weight of units of butadiene; n and n C: 0.5 to 15% by weight of a particulate polymer C distributed in the hard matrix A and comprising, based on C, n C1: 80 to 99% by weight of units of methyl methacrylate, n C2: 0.5 to 15% by weight of units of an ester of acrylic acid, n C3: 0.5 to 5% by weight of units of a crosslinking monomer copolymerizable with C1 and C2, and n C4: up to 10% by weight of units of a polar monomer selected from (meth)acrylic acid, hydroxyethyl (meth)acrylate and dimethylaminoethyl (meth)acrylate, n the median particle size of C being from 50 to 50,000 nm.
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