| abstract |
Particulates of a superabsorbent partially, neutralized acrylic polymer, e.g., polyacrylic acid, having a mean particle size ranging from 100 to 500 μm, essentially monodisperse and essentially devoid of fines having a particle size of less than 100 μm, having a nonuniformly surfaced spheroidal particle morphology and containing less than 50 ppm of residual monomer, well suited for a variety of hygienic applications, are prepared by (i) polymerizing a suspension of an acrylic monomer charge I in an organic medium and producing a suspension of acrylic polymer gel particles, (ii) next absorbing a second acrylic monomer charge II into the gel particles, (iii) polymerizing in the gel particles the second acrylic monomer charge II, (iv) azeotropically dehydrating the acrylic polymer particulates thus obtained, (v) then treating the dehydrated particulates with hydrogen peroxide, and (vi) drying the superabsorbent particulates thus treated. |