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filingDate 1991-11-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1995-01-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-5384215-A
titleOfInvention Polypyrrole shaped material, process for production thereof, and secondary battery
abstract PCT No. PCT/JP91/01559 Sec. 371 Date May 13, 1993 Sec. 102(e) Date May 13, 1993 PCT Filed Nov. 14, 1991 PCT Pub. No. WO92/09112 PCT Pub. Date May 29, 1992.A polypyrrole shaped material characterized in that when the polypyrrole shaped material is assembled into a tri-electrode cell comprising the polypyrrole shaped material as a positive electrode, platinum as a negative electrode, a lithium metal as a reference electrode and LiClO4 or LiBF4 as an electrolyte and said tri-electrode and cell are subjected to discharging at a current density of 10 mA/cm2 and controlled-potential charging at 3.6 V, (i) at the completion of the discharging, the concentration of chlorine or fluorine in the polypyrrole shaped material is 30% or below of that at the completion of the charging, and (ii) at the completion of the charging, the distribution of chlorine or fluorine in the thickness direction of the polypyrrole shaped material is 50% or less. This polypyrrole shaped material enables charging and discharging at high current densities and has large charging and discharging capacities, and can therefore be utilized as an electrode for secondary battery.
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