http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5262496-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_50907fc1b392e2bf592f74fb8123032d |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09D175-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G18-6208 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F8-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08C19-40 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09D175-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G18-62 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F8-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08C19-40 |
filingDate | 1993-04-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 1993-11-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_596779b87f4b37a12b0a6112c6339dba http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a1975f9b6ec7e71b2f02fd1106c5298e http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5dece4f9c9f84db035c2bc810f35ca23 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_247ffe3d66327ea974becbd638740dea |
publicationDate | 1993-11-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-5262496-A |
titleOfInvention | Hydroxyl functional derivatives of epoxidized diene polymers and process for making them |
abstract | A process for making polymers of conjugated dienes which contain hydroxyl groups, including highly reactive primary hydroxyl groups, in the diene blocks which comprises (a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer, (b) optionally partially hydrogenating said precursor polymer, (c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from at least 0.1 Meq/g polymer, and (d) reacting the epoxidized polymer with an alcohol having one unprotected hydroxyl group in a solvent in the presence of a Lewis acid selected from the group consisting of MXn where M is selected from the group consisting of boron, aluminum, iron and tin, and X is a halogen, and organic complexes of such acids. A diene polymer containing 0.01 to 15 Meq/g polymer of hydroxyl group, preferably including highly reactive primary hydroxyl groups, and comprised of ether-alcohol units of the formula <IMAGE> (F) or <IMAGE> (G) where R is selected from the group consisting of alkyl radicals containing up to 10 carbon atoms, monohydric and dihydric alcohol groups and carbonate groups; and R1 and R2 are hydrogen or alkyl radicals wherein in (G) only one of R1 or R2 is hydrogen. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-7932409-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2008293913-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-7887926-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2009232764-A1 |
priorityDate | 1992-04-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 227.