http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5144039-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_70d9f5d9fa76ffc0e26a93e9211015b8 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B2200-07 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D249-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-143 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D233-56 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D231-12 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-143 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D249-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D521-00 |
filingDate | 1990-01-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 1992-09-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bb0a88c06e0b1e6e480b14dc15568130 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2494ce5c2602d026c5637e492adbd617 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_96970a52bb2c3ead056b35837b68e8d4 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_0a4d7a4f114ceada74f2dab23be9736f |
publicationDate | 1992-09-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-5144039-A |
titleOfInvention | Process for producing optically active alcohol |
abstract | The process for producing an optically active alcohol of the present invention comprises allowing n (A) an optically active amino alcohol represented by the general formula (I) ##STR1## (R 1 is an aryl group, R 2 is a lower alkyl group, R 3 is a hydrogen atom or a lower alkyl group, and the carbon atoms having a mark * are each an asymmetric carbon atom) and an acid, or a salt of the optically active amino alcohol (I) and an acid, n (B) a metal borohydride, and n (C) at least one member selected from the group consisting of water, sulfides, cyclic ethers, ethers of mono alcohol to react with n a prochiral ketone represented by the general formula (II) ##STR2## [R 4 and R 5 are different and each a lower alkyl group, an aryl group, an aralkyl group or a 2-substituted-1-triazoleethylene group represented by the general formula (III) ##STR3## (R 6 is a halogen- or haloalkyl-substituted or unsubstituted phenyl group or a cycloalkyl group)]. n According to the present invention, the optically active alcohol (IV) can be obtained with good efficiency and a high optical purity. Therefore, the present process is advantageous in industrial application, in particular. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6156940-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6025531-A |
priorityDate | 1989-01-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
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