http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5071966-A
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_01c1e0bc0628f76dea731cda5a666ca1 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F7-1804 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-18 |
filingDate | 1990-01-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 1991-12-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bf18077a89573d7c45660d3455fd52e5 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_43b07f6f50e2aee2fd0eb414fc813958 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1f63840f00103427880082f2d5d44ed3 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6ea45cd80f9d955df0167686da0f4d62 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d3dbab353fb95f932ae1d50caafeba46 |
publicationDate | 1991-12-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-5071966-A |
titleOfInvention | Process for preparing an enol silyl ether compound |
abstract | A process for preparing an enol silyl ether compound from a diazoacetoacetic acid ester having the general formula (IV): ##STR1## wherein R 1 is a lower alkyl group having 1 to 6 carbon atoms, phenyl group, a substituted phenyl group, an aralkyl group or allyl group, and R 2 , R 3 and R 4 are the same or mutually different and each is a lower alkyl group having 1 to 6 carbon atoms, which comprises reacting a diazoacetoacetic acid ester having the general formula (I): ##STR2## wherein R 1 is the same as defined above, with a trialkylsilyl chloride having the general formula (II): ##STR3## wherein R 2 , R 3 and R 4 are the same as defined above, in an inert solvent in the presence of an organic base and an alkali halide having the general formula (III): n n MX (III) n n wherein M is an alkaline metal and X is bromine atom or iodine atom. The desired compound is useful as an intermediate for synthesis of carbapenem β-lactam antibiotics. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2007092460-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2003185769-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5340927-A |
priorityDate | 1989-01-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 104.