| abstract |
A process for forming carbides of silicon or metals in fine powder or whisker form. The process comprises forming a substantially uniform and non-agglomerated dispersion of a microfine powder of an oxide of silicon or a carbide-forming metal within a matrix of a polymer, carbonizing the oxide-containing polymer in an inert atmosphere and heating the carbonized product at high temperature to cause the oxide to react with carbon to form a carbide. The polymer must have a molecular weight of at least 10,000, a high carbon yield of at least 30% by weight, and a chemical structure which is infusible or capable of being rendered infusible. The preferred polymers are polyacrylonitrile, cellulose and polyvinyl alcohol, but other polymers with similar characteristics can be employed. The process is relatively inexpensive and gives an extremely finely divided product of high purity. |