http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4941931-A

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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C06B23-00
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C06B45-10
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C06B45-10
filingDate 1983-08-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1990-07-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d47e195b65dc7d5968d5ad7131a4d4e2
publicationDate 1990-07-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4941931-A
titleOfInvention Gas-generated expandable beads as burning rate accelerators
abstract Mechanical enhancement of the burning rate of solid propellants is achieved by the incorporation of limited percentages of gas-generated-expandable beads into the solid propellant composition during propellant mixing and which are chemically crosslinked during propellant curing to a solid propellant grain. When the flame front reaches an individual bead during propellant grain burning, the bead which contains a blowing agent selected from 4-toluenesulfonyl hydrazide and 4,4'-oxybis(benzenesulfonyl hydrazide) and coated with a bead forming material consisting of about 95 parts by weight hydroxyl-terminated polybutadiene prepolymer, of about 5 parts by weight of trimethylolpropane, and of about 6 parts by weight of isophorone diisocyanate expands to several times its volume and ruptures. Bead expansion or rupture causes a disruption of the propellant's surface, and the flame can penetrate into the propellant. The penetration results in a major increase in burning rate. An increase in propellant density and an improvement in mechanical properties are achieved as a result of the beads being chemically crosslinked during propellant curing after being first physically dispersed in the propellant composition during propellant mixing.
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