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filingDate 1988-07-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1989-05-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1989-05-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4827054-A
titleOfInvention Method for synthesizing 2,2-bis(4-fluorophenyl)-hexafluoropropane and method for using same to synthesize poly(arylethers) and poly (arylthioethers)
abstract Novel processes are provided for synthesizing 2,2-bis(4-fluorophenyl)hexafluoropropane and the use of this synthesized monomer in polymerization reactions to form poly(arylethers) and poly(arylthioethers). Synthesis of 2,2-bis(4-fluorophenyl)hexafluoropropane involves converting the commonly available compound Bisphenol AF to an amino-substituted form, followed by treatment with borofluoric acid and a nitrite, and then an aromatic solvent to obtain the monomer. The monomer can be mixed with either a dihydroxy diphenyl hexafluoropropane or a dimercapto diphenyl hexafluorpropane to cause a nucleophilic substitution reaction, thereby yielding the desired poly(arylether) or poly(arylthioether).
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