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filingDate 1988-04-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1989-05-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1989-05-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4827045-A
titleOfInvention Etherification of extracted crude methanol and conversion of raffinate
abstract An improved process for reacting crude aqueous methanol feedstock with iso-olefinic hydrocarbons to produce C5+ methyl tertiary-alkly ethers, which comprises: contacting the aqueous methanol feedstock with a liquid hydrocarbon extractant rich in C4+ iso-alkene under liquid extraction conditons; recovering an organic extract phase comprising the hydrocarbon extractant and a major amount of methanol introduced in the feedstock; reacting the extracted methanol and C4+ isoalkene in contact with an acid etherification catalyst under catalytic reaction conditions to produce ether product; recovering an aqueous methanol raffinate phase containing the major amount of water introduced with the feedstock and a minor amount of feedstock methanol; and converting methanol from the aqueous raffinate phase to produce hydrocarbons.
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