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filingDate 1987-10-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1989-03-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5c3ce4a9aea3ac0ec8a62b521a9ccb6f
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publicationDate 1989-03-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4816541-A
titleOfInvention Method for the preparation of SiH-containing organopolysiloxanes
abstract A method is disclosed for the synthesis of SiH-containing organopolysiloxanes from the corresponding Si-halogen-containing organopolysiloxanes by the reaction with metal hydrides in a liquid reaction medium. The method has the following combiniation of characteristics: (a) the use of a metal hydride being LiH, NaH, KH, CaH2 or MgH2; (b) the use of ethers as reaction medium; (c) the continuous removal of the metal halide depositing on the surface of the metal hydride particles during the reaction by the action of mechanical energy or ultrasound with formation of a fresh surface. The reaction proceeds practically quantitatively and at low temperatures. It can be applied with particular advantage to industrially obtained mixtures of alpha , omega -dichloroorganopolysiloxanes.
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