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filingDate 1987-11-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1989-02-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a993af9f6f239d8dfa3b4f6d439460c4
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publicationDate 1989-02-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4803305-A
titleOfInvention Isobutane oxidation in the presence of a soluble iron complex as catalyst
abstract The oxidation of isobutane in the presence of a novel, soluble catalyst of the formula Fe3O(Pivalate)6(MeOH)3Cl is disclosed. Tertiary-Butyl alcohol, tertiary-butyl hydroperoxide, and acetone are produced. A significant increase in isobutane conversion is obtained without a large decrease in selectivity to tertiary-butyl alcohol and tertiary-butyl hydroperoxide using a small amount of catalyst. Tertiary-butyl alcohol is useful as a gasoline additive and tertiary-butyl hydroperoxide is used for the production of propylene oxide. Acetone has a variety of uses as well.
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