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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C10G67-04
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C10G67-04
filingDate 1987-05-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1988-12-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e6ee559166f714ec3a3351324668ba12
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6536c789e18ea04fcf3d3fb957c58db5
publicationDate 1988-12-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4790930-A
titleOfInvention Two-step heterocyclic nitrogen extraction from petroleum oils
abstract A process is disclosed for the removal of basic heterocyclic nitrogen compounds from a petroleum crude oil or fraction thereof which comprises first treating the petroleum crude oil or fraction thereof rich in basic heterocyclic nitrogen compounds in a two-phase extraction zone with an extractant consisting essentially of an aqueous solution of a lower carboxylic acid, preferably having between 1 and 15 carbon atoms. The extractant complexes the basic heterocyclic nitrogen compounds to produce a stream of petroleum crude oil or fraction thereof having a smaller content of heterocyclic nitrogen compounds and a stream comprising the lower carboxylic acid extractant with an increased quantity of basic heterocyclic nitrogen compounds. The petroleum crude oil or fraction thereof possessing a reduced quantity of heterocyclic nitrogen compounds is hydrotreated in the presence of hydrogen and a hydrotreating catalyst to further remove the basic heterocyclic nitrogen compounds. The extractant stream is treated in an extractant separation zone to renovate the extractant for recycle to the two-phase extractant zone, substantially free of removed basic heterocyclic nitrogen compounds.
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