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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C201-08
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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-36
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D215-12
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D207-00
filingDate 1984-12-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1988-11-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_cd32eef9d5f81556244b2de6c70677a0
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_8a7c3b9769ebd884be2aa78cbc3937e0
publicationDate 1988-11-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4782184-A
titleOfInvention Method for making ethynylated aromatic compounds
abstract A method is disclosed for making amino-substituted ethynlated biphenyl compounds, which includes selectively nitrating symmetrically substituted biphenyl compounds, reacting the resulting nitro-substituted aromatic compound with a copper acetylide to replace the iodo substituents with ethynyl groups, and then reacting the ethynylated, nitro-substituted aromatic compound with hydrogen in the gas phase to reduce the nitro groups to amino groups. The preferred nitrating agent is nitronium trifluoromethanesulfonate, made by reaction of anhydrous nitric acid with trifluoromethanesulfonic anhydride in an anhydrous solvent.
priorityDate 1982-12-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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