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filingDate 1986-10-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1988-08-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1988-08-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4764622-A
titleOfInvention Light-collecting coumarin derivatives
abstract A light-collecting system, which contains a coumarin derivative of the formula <IMAGE> in which T denotes O or NR4, R4 represents hydrogen, optionally substituted aryl, cycloalkyl or aralkyl, R1 denotes a carbocyclic or heterocyclic 5 or 6 membered ring bonded via a C.atom, or a 5 or 6 membered heterocyclic ring which is bonded via a N atom and is rotationally asymmetrical to an axis placed through the coumarin/N-heterocyclic bond, the 5 or 6 membered rings may carry non-ionic substituents and for an optionally substituted benzene ring or naphthalene ring to be fused to the said rings; X signifies <IMAGE> or -OR2', R2 represents hydrogen, alkyl, cycloalkyl, aralkyl or aryl, hydrocarbon radicals may be substituted, and R3, in addition to having the definitions given for R2, also signifies a radical of the formulae R6-(X)n-CO- or R7-(X)n-SO2- R6 and R7 represent alkyl, cycloalkyl, aryl or aralkyl, the hydrocarbon radicals may be substituted, X represents NH or O and n represents O or 1, or R2 and R3 together with the N atom and optionally with the inclusion of further hetero-atoms form a 5 or 6 membered ring, this ring may carry non-ionic substituents and an optionally substituted benzene ring or naphthalene ring may be fused thereto, or R2 and R3 together form a di-unsaturated radical of the formula <IMAGE> R8 represents optionally substituted alkyl, aryl, cycloalkyl or aralkyl, and R2' signifies optionally substituted alkyl, alkenyl, cycloalkyl, aryl or aralkyl, and their use in light-collecting systems.
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