abstract |
1-Butenes are selectively produced via the dimerization of 1-olefins in the presence of novel organotantalum catalysts comprising tantalum and a silyl-substituted cyclopentadienyl moiety having the formula C 5 H 5-x (SiR 6 3 ) x , wherein each R 6 may be the same or different and is hydrogen, alkyl, cycloalkyl, aryl, aralkyl or alkoxy, and x is an integer from 1 to 5. |