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filingDate 1984-08-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1986-06-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_dc233dd915c157b95185f6b0c8d2f172
publicationDate 1986-06-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4595493-A
titleOfInvention Process for the flotation of base metal sulfide minerals in acid, neutral or mildly alkaline circuits
abstract A process for the beneficiation of base metal sulfide mineral values from base metal sulfide ores with selective rejection of gangue sulfide minerals at pH values of below about 10.0 by froth flotation is disclosed. The process includes the use of a new and improved collector which at pH values below 10.0 exhibits unexpectedly high collector activity for base metal sulfide minerals such as copper, lead and zinc and selectively rejects gangue sulfide minerals, such as pyrite and pyrrhotite. The collector for base metal sulfide mineral values for use in the process comprises at least one hydrocarboxycarbonyl thionocarbamate compound having the formula: <IMAGE> wherein R1 is C1-C6 alkyl or phenyl and R2 is C1-C8 alkyl. In a preferred embodiment of the present invention, the froth flotation is conducted under acid pH conditions by adjusting the pH of the flotation slurry with sulfuric acid. The process provides excellent metallurgical recoveries of copper sulfide mineral values of high grade at a substantial reduction in lime consumption and reagents costs associated with prior art flotation separation methods. Bulk sulfide flotation methods are also disclosed.
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