| abstract |
A catalyst having heteropoly-acid structure and the general formula: MoaVbPcCudAseXfOg wherein, X represents one or more elements selected from the group consisting of tin, lead, cerium, cobalt, iron, zirconium, thorium, tungsten, germanium, nickel, rhenium, bismuth, antimony, chromium, boron, magnesium, silver, aluminum, zinc and titanium and a, b, c, d, e, f and g represent the atomic ratio of the elements where, a is 10, b is a number of 3 or less than 3 excluding 0, c is a number of 0.5 to 6, d is a number of 3 or less than 3 excluding 0, e is a number of 3 or less than 3 excluding 0, f is a number of 0 to 3, g is a number determined depending on the valency and atomic ratio of other elements. There is also provided a process for producing methacrylic acid by oxidizing methacrolein with molecular oxygen or molecular oxygen-containing gas in the vapor phase in the presence of the catalyst defined above. |