abstract |
A stabilized polyphenylene sulfide is provided which comprises a recurring unit <IMAGE> wherein the average n between foreign units is greater than about 5, and about 0.05 to about 10 mole % per phenylene sulfide unit of an aromatic constituent chemically bonded with said polyphenylene sulfide chain, said aromatic constituent containing an electron attractive group selected from the group consisting of -SO2-, -CO-, -NO2, -SO3R, -COOR, wherein R is H, lower aliphatic hydrocarbon groups, aromatic hydrocarbon groups or alkaline metals, and -CONH-, and said stabilized polyphenylene sulfide has a melting point in the range of about 250 DEG C. to about 350 DEG C. Also provided is a method for preparing stabilized polyphenylene sulfide comprising preparing a polyphenylene sulfide consisting mainly of a recurring unit <IMAGE> wherein the degree of polymerization of said recurring unit is greater than about 20, and reacting said polyphenylene sulfide with about 0.05 to about 20 mole % per said phenylene sulfide unit of a halogenated aromatic compound having an electron attractive group. |