http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4419195-A
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_c0bdbaa7d1404425011d1b246ed5628a |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C25B3-13 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C25B3-23 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C25B3-23 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C25B3-13 |
filingDate | 1982-01-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 1983-12-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ed457e602887fd615d4026b7ca525dbd |
publicationDate | 1983-12-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-4419195-A |
titleOfInvention | Electrolytic recovery of cobalt oxo catalysts |
abstract | According to one embodiment of the improved process of this invention, dicobalt octacarbonyl is produced in liquid medium by subjecting an aqueous solution of a tetracarbonylcobaltate salt in the presence of a solvent for dicobalt octacarbonyl to an externally applied voltage and electrical current at a magnitude and for a time sufficient to convert at least a portion of the tetracarbonylcobaltate anion to dicobalt octacarbonyl which is efficiently extracted into said solvent, thereby producing a solvent phase which can be recovered and passed to a cobalt-catalyzed olefin hydroformylation reaction zone as the source of at least a portion of the catalyst and olefin required in the olefin hydroformylation reaction to form the corresponding aldehydes. It has been surprisingly found that such a two-phase electrolysis can be performed to efficiently provide high yields of dicobalt octacarbonyl while substantially avoiding the fouling problems associated with aqueous-phase electrolysis. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6777503-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-11105007-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5059718-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2003013819-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-102018202335-A1 |
priorityDate | 1982-01-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 56.