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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F7-20
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-20
filingDate 1982-09-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1983-09-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_172cd2b12d53566509712d15ded3eb90
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b5e567fee0b00f6ebf89dd9889dd2f90
publicationDate 1983-09-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4402796-A
titleOfInvention Separation of chlorosilanes by liquid extraction
abstract This invention relates to a method of separating close-boiling chlorosilanes from mixtures by employing the technique of liquid extraction with sulfolane and a hydrocarbon compound as co-solvents. The hydrocarbon compound employed is substantially immiscible in sulfolane and is present in sufficient amounts so that two liquid phases are formed, one being suloflane-rich and the other being hydrocarbon-rich. The mixture of chlorosilanes is intimately mixed with the two solvents and allowed to partition between the two phases. The preferred liquid extraction procedure is where the sulfolane and hydrocarbon solvent are in a countercurrent relationship within an extraction tower. Experimentally determined selectivity coefficients show that mixtures of (1) dimethyldichlorosilane and methyltrichlorosilane, (2) phenylmethyldichlorosilane and phenyltrichlorosilane, and (3) trimethylchlorosilane and tetrachlorosilane can be successfully separated by the techniques of this invention.
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