http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4401598-A
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_d669af06cb2abbcd6823699582a97002 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/G01F23-245 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/G01F23-0023 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/G01F23-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/G01F23-24 |
filingDate | 1981-10-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 1983-08-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_8b892a4cf122d740f05455058fd501b6 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4d90ed72944be46a98d6a2b6b0ae600c |
publicationDate | 1983-08-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-4401598-A |
titleOfInvention | Production of organosilicon compounds having azido groups |
abstract | There are prepared azido groups containing organosilicon compounds of the formula ##EQU1## where R is a divalent hydrocarbon group having 1 to 8 carbon atoms which is free from ethylenically unsaturated bonds and whose carbon chain in a given case, is interrupted once by --O--, --S--, or --NR 3 where R 3 is hydrogen, methyl, ethyl, or phenyl, n R 1 is a univalent alkyl group having 1 to 3 carbon atoms, phenyl, benzyl, or tolyl, n R 2 is an alkyl group having 1 to 4 carbon atoms, phenyl, benzyl, or an alkoxyalkyl group having a total of up to four carbon atoms, n m is zero, 1, 2, or 3, and n n is zero, 1 or 2 whereby m<3-n, by reacting a halosilane of the formula n n X--R--SiR.sub.n.sup.1 (OR.sup.2).sub.3-n, II n n in which X is chlorine or bromine and the other symbols are as defined above with an azide of the formula n n MN.sub.3 III n n in which M is lithium, sodium, potassium, or ammonium, whereby in a give case, there is used a phase transfer catalyst whereupon there is carried out a hydrolysis or partial hydrolysis. Alternatively the hydrolysis or partial hydrolysis can take place first wherein there is first carried out the hydrolysis of one or more alkoxysilyl groups --OR 2 and subsequently there is carried out the reaction with the azide. The organosilicon compounds are valuable intermediates and also can be used as coupling agents for preparing silica reinforced rubber. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5405985-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-3674702-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5461691-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5085938-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5137626-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4992306-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5468893-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5663396-A |
priorityDate | 1980-10-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 162.