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grantDate 1983-06-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1983-06-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4388438-A
titleOfInvention Aqueous dispersions of copolymers of styrene dibutyl maleate and acrylic or methacrylic acid or monobutyl maleate and method for preparation thereof
abstract The method of preparing aqueous dispersions of copolymers of styrene dibutyl maleate and acrylic or methacrylic acid or monobutyl maleate consists in adding a monomer mixture comprising styrene in the amount of 40-90% by weight, dibutyl maleate in the amount of 10-60% by weight acrylic or methacrylic acid or monobutyl maleate in the amount of 1.0-10.0% by weight in relation to the sum of styrene monomer and dibutyl maleate into the emulsion water known constituents such as: ionic emulsifier - non-ionic emulsifier, buffer, sodium acrylate, N-methylolmethacrylamide to which, prior to polymerization, an alkylene glycol comprising 2-6 carbon atoms in the alkylene group is added. The alkylene glycol is added in the amount of 1-6% by weight in relation to the sum of styrene monomer and dibutyl maleate while, the ratio of alkylene glycol to the methacrylic acid or monobutyl maleate contained in the monomer mixture is 1:0.2-2. The polymerization process is conducted at a temperature of 70 DEG -90 DEG C. up to complete reaction of the monomers, then the reaction mixture is cooled down to a temperature of 10 DEG -30 DEG C. and a single dose of concentrated ammonia water is added to adjust the pH of the composition to about 9.5. The obtained dispersions are used for thermal coating of building materials for protective and decorative purposes.
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