abstract |
This invention concerns a process of making alkanols and particularly methanol which comprises reacting a mixture of CO and H 2 at a pressure of about 500 psig or greater and at a temperature of at least 150° C. in the presence of a catalyst system comprising a ruthenium-containing compound and a rhenium- or manganese-containing compound and a quaternary phosphonium or ammonium base or salt and in the presence of an inert, oxygenated solvent. |