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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-06
filingDate 1980-06-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1981-10-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4f24dfa4eb5b27c7105966034cbec94b
publicationDate 1981-10-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4296261-A
titleOfInvention Process for the manufacture of ethanol from ethylene
abstract A process for the manufacture of C 2 -C 5 alcohols from C 2 -C 5 olefins by the indirect hydration method is disclosed. The process comprises the steps of (a) treating a C 2 -C 5 olefin in an absorption zone in admixture with a C 2 -C 5 alkyl hydrogen sulfate at conditions to form a C 2 -C 5 dialkyl sulfate; (b) treating said dialkyl sulfate in a hydrolyzing zone in admixture with a measured amount of water at conditions effecting the partial hydrolysis of said dialkyl sulfate and the formation of a C 2 -C 5 alkyl hydrogen sulfate and a C 2 -C 5 alcohol; (c) separating the alcohol; and (d) recycling the alkyl hydrogen sulfate to said absorption zone, and treating said C 2 -C 5 olefin in admixture therewith in accordance with step (a). The practice of this invention substantially obviates the formation of sulfuric acid and the required reconcentration thereof.
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