abstract |
An improved hydroformylation process for preparing aldehydes by reacting olefins with synthesis gas (H2 and CO) under heating and pressure is disclosed. The hydroformylation is carried out in the presence of a platinum catalyst, and assitant composed of a halide of a metal of the group IVb of the Periodic Table and a reaction promotor composed of a specific bidentate ligand of the formula R2X-Z-Y-Z-X-R'2. In this reaction, the platinum catalyst exerts a high activity, and an aldehyde mixture containing a linear isomer at a very high ratio of content is obtained as a product. |