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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C25B11-054
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C25B1-00
filingDate 1978-10-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1980-09-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ab29755379e91f310f92c04660c25c1b
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_617c046911cd346000c2d35d2cf36309
publicationDate 1980-09-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4222826-A
titleOfInvention Process for oxidizing vanadium and/or uranium
abstract The present invention provides a process for rapidly and efficiently oxidizing either or both vanadium and uranium from the trivalent and guadrivalent oxidation states, respectively, to the pentavelent and hexavalent oxidation states, respectively, through the use of a special electrode. The electrode is produced by anodically treating a substrate material selected from the group of titanium, zirconium, niobium, hafnium and alloys thereof in an aqueous electrolyte. The electrolyte comprises an aqueous solution of manganous ion in a concentration of from about 15 to 50 gm/l and from about 10 to 40 gm/l sulfuric acid. Manganese dioxide is electrodeposited on the substrate to form the electrode. The manganese dioxide coated electrode then is placed in an oxidation cell as an anode wherein it is potentiostaticly controlled to oxidize either or both vanadium and uranium without significant anode deterioration and without oxygen generation at the anode.
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