| abstract |
Suitable glass-ceramic base compositions, including some silicates, aluminosilicates, lithium aluminosilicates, and boroaluminates, are modified by the addition of suitable quantities of transition metal oxides prior to melting and forming into thermally-crystallizable glass articles. Appropriate crystallization and post-crystallization heat treatments are thereafter employed to cause crystallization of the articles and the formation and growth of films thereon, which films are characterized by the presence of transition metal compounds, typically of spinel structure, therein. Such films demonstrate useful electrical, magnetic, catalytic and/or light-absorptive properties. |