abstract |
A three surfactant system usable in high temperature petroleum formations containing water having from about 200 to about 14,000 parts per million polyvalent ions such as calcium and/or magnesium dissolved therein and a pH of from 5 to 9, and a method of using said surfactant system for recovering petroleum from high temperature subterranean petroleum-containing formations. The three component surfactant system comprises (1) water-soluble salt of an alkyl or alkylaryl sulfonate wherein the alkyl chain may have from 5 to 25 carbon atoms, (2) a phosphate ester surfactant with an average molecular weight not to exceed 1000, and (3) a surfactant having the following betaine related structure: <IMAGE> wherein R is an alkyl group having from 12 to 24 carbon atoms, and n is an integer from one to five. The surfactant combination is stable up to at least 225 DEG F and resistant to bacterial attack and inhibits scale formation. |