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filingDate 1973-05-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1976-01-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1976-01-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-3933929-A
titleOfInvention Process for the purification of p-nitrophenol
abstract In a purification process for p-nitrophenol obtained by nitration of phenol, separation of crude nitrophenols, steam distillation to remove o-nitrophenol, and cooling the broth obtained when it contains more than 0.5% sodium bisulphite and is at pH 5.4 to 6.4 to deposit crystals of p-nitrophenol, an improvement consists in stirring the crystals with water at 55 DEG -85 DEG C to give a mixture containing 10-40% excess of p-nitrophenol over the solubility at that temperature, separating the upper layer of p-nitrophenol in water obtained, cooling it to 40 DEG -50 DEG C and separating the layer of water in p-nitrophenol, cooling the latter to below 30 DEG C and collecting the crystals deposited.
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