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filingDate 1974-03-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1976-01-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5d2429e5bf8e7ce14ac0e326541373e3
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publicationDate 1976-01-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-3932511-A
titleOfInvention Preparation of cyclohexane-1,3-dione and of alkyl-substituted derivatives thereof
abstract Process for the preparation of cyclohexane-1,3-diones of the formula ##SPC1## n Wherein R 1 -R 8 , which are the same or different, are each hydrogen or an alkyl group containing up to 6 carbon atoms and the total number of carbon atoms of R 1 -R 8 is not more than 12 carbon atoms, comprising contacting in the gaseous state a delta-keto ester of the formula ##EQU1## wherein R 1 -R 8 are as defined above and R 9 is an alkyl, cycloalkyl, or monocyclic or bicyclic arylalkyl or aryl group containing up to 12 carbon atoms, with a thermally stable solid material having an internal surface area of from about 100 tot 1500 m 2 /gm. at a temperature of from 100 °C to 500 °C.
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