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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D271-113
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filingDate 1970-08-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1974-11-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1981812aebc5e911f55c6457a2a08787
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f77b2264584cc384dc86ec675d4f253a
publicationDate 1974-11-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-3846439-A
titleOfInvention Process for the preparation of 3-phenyl-5-t-butyl-2-oxadiazolones
abstract 3-(2,4-Dichlorophenyl)-5-t-butyl-1,3,4-oxadiazol-2-ones of the formula: IN WHICH R represents a hydrogen atom or an alkoxy group containing one to four carbon atoms, which possess herbicidal properties, are prepared by a new process involving reaction of a halogenonitrobenzene of the formula: IN WHICH Y represents a halogen atom and R is as defined, with an alkali metal salt of 5-t-butyl-1,3,4-oxadiazol-2-one, reduction of the nitro group in the resulting 3-(2-nitro-4chlorophenyl)-5-t-butyl-1,3,4-oxadiazol-2-one, which may carry an alkoxy substituent R in the 5-position of the benzene ring, to a primary amino group, and replacement of the amino group in the resulting 3-(2-amino-4-chlorophenyl)-5-t-butyl-1,3,4-oxadiazol-2one by a chlorine atom by reaction of cuprous chloride with a diazomium salt derived from the amino compound. The process avoids the use of phosgene - an awkward reagent hitherto employed in the production of the 3-(2,4-dichlorophenyl)-5-t-butyl-1,3,4oxadiazol-2-ones.
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priorityDate 1970-04-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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