| Predicate |
Object |
| assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_9e5302e08e56037ff7bc5c9b6fcc29f9 |
| classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-70
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C49-203
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-293
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-00
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D295-03 |
| classificationIPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D295-02 |
| classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-203
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-70
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-145
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D295-03 |
| filingDate |
1970-04-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate |
1973-08-28-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9a11d2d7e9017d2c1862897eed9ab2af
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1aad94f7170327bc56af5949e356ac74
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ea86c9e1778cf47bbee91c6eef0cc840 |
| publicationDate |
1973-08-28-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber |
US-3755451-A |
| titleOfInvention |
Exchange reactions of octadienyl esters with active hydrogen compounds |
| abstract |
3-OCTA-1,7-DIENYL ACETATE IS READILY ISOMERIZED TO 1-OCTA2,7-DIENYL ACETATE IN THE PRESENCE OF PALLADIUM CATALYSTS ALONE AND AT A RAPID RATE WHEN A TERTIARY AMINE IS ADDED. THIS SAME ALLYLIC ISOMERIZATION OCCURS WITH BUTENYL ACETATES. ALLYLIC ALCOHOLS SUCH AS 2-OCTA-1,7-DIENOL ALSO UNDERGO THIS ISOMERIZATION. 1-ACETOXY-2,7-OCTADIENE AND 1-OCTA-2,7-DIENOL ARE EACH INTERMEDIATES IN THE PROCESS FOR THE PRODUCTION OF LINEAR OCTANOL. THE CATALYST SYSTEM IS ALSO USEFUL FOR REPLACING THE FUNCTIONAL GROUPS IN AN ALLYLIC SYSTEM. FOR EXAMPLE, OCTADIENYL ESTERS CAN BE CONVERTED INTO (1) OCTADIENYL AMINES VIA REACTION WITH PRIMARY OR SECONDARY AMINES, (2) OCTADIENYL ETHERS VIA REACTION WITH ALCOHOLS, (3) OTHER OCTADIENYL ESTERS BY REACTION WITH OTHER CARBOXYLIC ACIDS AND (4) USED TO EXTEND A CARBON CHAIN WHEN REACTED WITH COMPOUNDS CONTAINING AN ACTIVATED CARBON-HYDROGEN BOND. |
| isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4117016-A
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4721820-A
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0254091-A1
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4044050-A
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-7423168-B2
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4310709-A
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-3865877-A
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2004092777-A1 |
| priorityDate |
1970-04-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type |
http://data.epo.org/linked-data/def/patent/Publication |