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publicationDate 1972-10-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-3700743-A
titleOfInvention Conversion of diacetylbenzenes to unsaturated derivatives
abstract The use of a solvent mixture consisting essentially of from 3070 volume percent dichloromethane with the balance being chloroform, has a profound beneficial effect on the yield of the Beta , Beta ''-dichlorobenzenediacrolein obtained by reaction of the complex of phosgene and N,N-dimethyl-formamide with m- or pdiacetylbenzene. The diacrolein products are readily converted to the corresponding diethynylbenzenes which are useful in the making of acetylenic polymers and copolymers.
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