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filingDate 1970-04-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1972-07-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1972-07-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-3679776-A
titleOfInvention Polymerization of hydrocarbon dienes with lithium-sodium alloys
abstract Conjugated hydrocarbon dienes are polymerized with lithiumsodium alloy initiator containing 0.1 to 90 mole percent sodium in a nonpolar medium at about -10*C. to 100*C. to yield the corresponding lithiopolydiene in which a desired high percentage of the repeating units have cis-1,4-structure. The lithiopolydienes can be used to prepare block copolymers of the ABA type in which the A units are polypivalolactone or a polymer of any other anionically polymerizable monomer and the B unit is a polydiene. The alloys can also be applied to prepare homopolydienes with high 1,4-cis structure, which are useful as vulcanizable elastomers.
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