| abstract |
AN L-3-HYDROXY-6-OXOMORPHINAN COMPOUND REPRESENTED BY THE FORMULA: 3-(O=),6-HO,10A-R,11-R1-MORPHINAN AND 3-(O=),6-HO,10A-R,11-R1-3,9,10,10A-TETRAHYDRO-4H-10,4A- IMINOETHANOPHENANTHRENE WHEREIN R REPRESENTS A HYDROGEN ATOM OR A HYDROXYL GROUP, R1 REPRESENTS AN ALLYL GROUP, A Y,Y-DIMETHYLALLYL GROUP OR A CYCLOPROPYLMETHYL GROUP AND F REPRESENTS THE PRESENCE OR ABSENCE OF A DOUBLE BOND, BEING USEFUL AS A NARCOTIC AGAINST, IS PREPARED BY INTRODUCING THE SUBSTITUENT AT THE N-POSITION. |