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filingDate 1969-03-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1972-01-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_aa852d5f0c3a478d244e84ac94518578
publicationDate 1972-01-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-3635840-A
titleOfInvention Polymerization catalyst
abstract A catalyst is prepared by calcining and thus coactivating with an oxygen-containing gas for a period of time to activate the same, to obtain disclosed results, the ingredients of a mass obtained by bringing together an organometal component, chromium oxide or a compound convertible by calcination to chromium oxide, in combination with at least one material selected from the group consisting of silica, alumina, zirconia, and thoria and a vanadium chelate component, e.g., vanadium acetylacetonate. The catalyst is suited to the polymerization of olefinic materials, especially 1-olefins and/or dienes to form polymers and copolymers, e.g., polyethylene. The catalyst permits polymerization of an alpha olefin to produce polymers having a considerably lower melt index at constant conditions than that earlier obtained with a catalyst omitting the vanadium acetylacetonate and productivities per unit of catalyst which are considerably greater than those obtained when the vanadium acetylacetonate is not present during coactivation.
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