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filingDate 1965-11-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1969-06-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a2962152c0c7ef57c34603d6ca5065f2
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publicationDate 1969-06-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-3450793-A
titleOfInvention Modified polycarbonates containing urethane groups
abstract Polycarbonates containing polyurethane blocks are made by reacting (a) a linear polyurethane substituted on the nitrogen atoms by alkyl, cycloalkyl or aryl radicals, or derived from piperazine, and containing reactive end groups with (b) a polycarbonate of a dihydric phenol containing reactive end groups or the ingredients necessary to produce such a polycarbonate. Preferably, the copolymer contains 0.01 to 10 mol. per cent of a polyurethane of molecular weight 1500 to 30,000. The process may comprise reacting a disecondary amine with phosgene or a bischloroformate of a dihydric phenol to produce a polyurethane with chloroformate end groups and either (i) reacting this with a dihydric phenol and phosgene or a bischloroformate of a dihydric phenol or (ii) reacting the polyurethane with a monohydric compound to convert the chloroformate end groups into carbonate ester groups and thereafter reacting the polyurethane with a polycarbonate or the ingredients necessary to produce the same by transesterification. Part of the dihydric phenol component of the polycarbonate may be replaced by an aliphatic or cycloaliphatic dihydric alcohol. In Examples (1)-(6), a polyurethane made by reacting bisphenol A bischloroformate with piperazine, N:N1 - diisopropyl hexamethylenediamine or N:N1 - dicyclohexyl hexamethylenediamine was reacted with bisphenol A, phosgene and p-tert.-butylphenol. In Examples (7) and (8) a polyurethane obtained by reacting N:N1-dicyclohexyl hexamethylenediamine with the bischloroformate of bisphenol A was reacted with phenol and the product reacted either with bisphenol A and diphenyl carbonate or with a polycarbonate of bisphenol A with phenolic end groups.
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