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filingDate 2020-01-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2022-04-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2022112146-A1
titleOfInvention METHODS AND SYSTEMS FOR PRODUCING HIGH PURITY METHANOL FROM CARBON DIOXIDE HYDROGENATION USING NaA MEMBRANE REACTOR
abstract The dehydration membrane reactor for methanol production from CO 2 hydrogenation includes one or more porous supports, a dehydration membrane on the one or more porous supports, and a catalyst layer on the dehydration membrane. The one or more porous supports include hollow ceramic fibers and the dehydration membrane includes NaA zeolite. The reactor is made by dip-coating the porous supports in a zeolite crystal seed solution and drying the coated porous support. The coated porous support is dried at about 80° C. and then heated to a temperature above about 200° C. The NaA zeolite membrane is then grown on the seeded support, and a catalyst layer is applied to the zeolite membrane. A feedstream including carbon dioxide and hydrogen is fed to the catalyst layer, where a product stream including methanol and water is evolved. The water is then removed from the product stream through the dehydration membrane to produce a high-purity methanol product.
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